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equal the target values, the of will approach a constant in the range l), rather t h a n going to 0. T h e sigmoid function output by a single perceptron (Figure 8.3) is, after a n ap= -f(z). However, propriate affine transformation, an odd function; t h a t is, the output of an MLP (with a hidden layer) does not have a comparable symmetry property. This can be easily seen from the fact t h a t its limits as z 4 *rn may take any value, shown in (8.8) and (8.9). This means t h a t the of (the - mlp(z) term), will likewise not have this symmetry, and the $ function for class 0 need not be symmetric with the function for class 1. For the second term of (2.5),

In addition to the effect of a solvent on the course of a polymerization because the solvent is a poor or good solvent for the polymer, solvents affect polymerization rates and molecular weights due to preferential solvation or other speci c interactions with either the reactants or transition state of the reaction or both The direction of the solvation effect is generally the same in polymerization as in the corresponding small molecule reaction and will not be considered in detail Thus polar solvents enhance the rate of a polymerization with a transition state more polar than the reactants Polar solvents are not desirable for reactions involving transition states that are less polar than the reactants The course of a polymerization can be dramatically affected by speci c interactions of a solvent with the functional groups of a reactant.

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The reactivity of a functional group can be altered by speci c interaction with solvent Thus solvents markedly affect the polymer molecular weight in the polymerization of adipic acid and hexamethylene diamine with certain ketone solvents yielding the highest molecular weights [Ogata, 1973] The molecular weight enhancement by ketones has been ascribed to an enhancement of the diamine nucleophilicity due possibly to a polar interaction between ketone and amine Alternately, the intermediate formation of an imine may be responsible, since imines can be formed from the diamine and ketone The imine would be expected to be more reactive than the amine toward the carboxylic acid..

The use of BlackBerrys can throw a monkey wrench into these solutions, mainly by just bypassing them. If malware resides on a BlackBerry and that BlackBerry connects directly to a PC, the malware doesn t get seen by a lot of these solutions. Also, mobile PCs that have antiviruses installed may not be able to receive antivirus definition updates in a timely manner (if they need to be on the LAN to receive updates). This problem requires a layered approach. Before we get into that, let s explore how a piece of malware can be placed on a BlackBerry and make its way to a corporate PC. The first step is that a piece of malware gets onto a noncorporate computer system. This can happen pretty easily with workers using their own computers from home. The user then copies that infected file to his BlackBerry. This can be done using the eOffice application I spoke about earlier. So, the user has an infected file on his home computer and he wants to transfer it to his work laptop. He decides to utilize the aforementioned eFile desktop program to do so. Figure 5.11 shows the user copying the infected file, called Blast, over to his BlackBerry with eFile.

Many, if not most, step polymerizations involve equilibrium reactions, and it becomes important to analyze how the equilibrium affects the extent of conversion and, more importantly, the polymer molecular weight. A polymerization in which the monomer(s) and polymer are in equilibrium is referred to as an equilibrium polymerization or reversible polymerization. A rst consideration is whether an equilibrium polymerization will yield high-molecularweight polymer if carried out in a closed system. By a closed system is meant one where none of the products of the forward reaction are removed. Nothing is done to push or drive the equilibrium point for the reaction system toward the polymer side. Under these conditions the concentrations of products (polymer and usually a small molecule such as water) build up until the rate of the reverse reaction becomes equal to the polymerization rate. The reverse reaction is referred to generally as a depolymerization reaction; other terms such as hydrolysis or glycolysis may be used as applicable in speci c systems. The polymer molecular weight is determined by the extent to which the forward reaction has proceeded when equilibrium is established. Consider an external acid-catalyzed polyesteri cation

the of we consider the asymptotic behavior. Taking limits and once again considering the variable we see that:

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