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111 What is the change in entropy when 07 m3 of C02 and 03 m3 of N 2 , each at 1 bar and 29815 K (25 C) blend to form a gas mixture at the same conditions Assume ideal gases 112 A vessel, divided into two parts by a partition, contains 4 mol of nitrogen gas at 34815 K (75 C) and 30 bar on one side and 25 mol of argon gas at 40315 K (130 C) and 20 bar on the other If the partition is removed and the gases mix adiabatically and completely, what is the change in entropy Assume nitrogen to be an ideal gas with Cv = (5/2)R and argon to be an ideal gas with Cv = (3/2)R 113 A stream of nitrogen flowing at the rate of 2 kg s-' and a stream of hydrogen flowing at the rate of 05 kg s-I mix adiabatically in a steady-flow process If the gases are assumed ideal, what is the rate of entropy increase as a result of the process 114 What is the ideal work for the separation of an equimolar mixture of methane and ethane at 44815 K (175 C) and 3 bar in a steady-flow process into product streams of the pure gases at 30815 K (35 C) and 1 bar if T, = 300 K 115 What is the work required for the separation of air (21-mol-% oxygen and 79-mol-% nitrogen) at 29815 K (25 C) and 1 bar in a steady-flow process into product streams of pure oxygen and nitrogen, also at 29815 K (25 C) and 1 bar, if the thermodynamic efficiency of the process is 5% and if T, = 300 K 116 What is the partial molar temperature What is the partial molar pressure Express results in relation to the T and P of the mixture 117 Show that: (a) The "partial molar mass" of a species in solution is equal to its molar mass (b) A partial speciJic property of a species in solution is obtained by division of the partial molar property by the molar mass of the species 118 If the molar density of a binary mixture is given by the empirical expression:.

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where directory is the directory to be unmounted For example,

119 For a ternary solution at constant T and P, the composition dependence of molar property M is given by:

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where M I , M2, and M3 are the values of M for pure species 1, 2, and 3, and C is a parameter independent of composition Determine expressions for M I , M 2 , and M 3 by application of Eq (117) As a partial check on your results, verify that they satisfy

CHAPTER 11 Solution Thermodynamics: Theory the summability relation, Eq (1111) For this correlating equation, what are the Mi at infinite dilution

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There s a catch to umount: If the file system is in use (that is, someone is currently accessing the contents of the file system or has a file open on the file system), you won t be able to unmount that file system To get around this, you have the following choices: You can use the lsof or fuser program to determine which processes are keeping the files open, and then kill them off or ask the process owners to stop what they re doing (Read about the kill parameter in fuser in the fuser man page) If you choose to kill the processes, be sure you understand the repercussions of doing so (read: Don t get fired for doing this) You can use the -f option with umount to force the unmount process It is especially useful for Network File System (NFS) type file systems that are no longer available Use the Lazy unmount This is specified with the -l option This option almost always works even when others fail It detaches the file system from the filesystem hierarchy immediately, and it cleans up all references to the file system as soon as the file system stops being busy The safest and most proper alternative is to bring the system down to singleuser mode and then unmount the file system In reality, of course, you don t always have this luxury

1110 A pure-component pressure pi for species i in a gas mixture may be defined as the pressure that species i would exert if it alone occupied the mixture volume Thus,

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